Micellar Iodide-Catalyzed Synthesis of Unprotected Aziridines from Styrenes and Ammonia

Micellar Iodide-Catalyzed Synthesis of Unprotected Aziridines from Styrenes and Ammonia

Aziridines from ammonia: Unprotected aziridines are formed from styrenes in one catalytic step. Ammonia is incorporated directly using an aqueous micellar solution containing bleach as oxidant and sub‐stoichiometric amounts of iodide (see picture).

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Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie (International ed.) 2008-02, Vol.47 (8), p.1477-1480
Hauptverfasser: Varszegi, Csaba, Ernst, Martin, van Laar, Frederik, Sels, Bert F, Schwab, Ekkehard, De Vos, Dirk E
Format: Artikel
Sprache:eng
Schlagworte:
alkenes
ammonia
Ammonia - chemistry
aziridines
Aziridines - chemical synthesis
Aziridines - chemistry
Catalysis
iodide
Iodides - chemistry
Iodine - chemistry
Micelles
Molecular Structure
Phenol - chemistry
Styrenes - chemistry
Surface-Active Agents - chemistry
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Beschreibung
Zusammenfassung:Aziridines from ammonia: Unprotected aziridines are formed from styrenes in one catalytic step. Ammonia is incorporated directly using an aqueous micellar solution containing bleach as oxidant and sub‐stoichiometric amounts of iodide (see picture).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200704772