Synthesis of 2-deoxy- d- arabino/ lyxo-hexopyranosyl disaccharides

Synthesis of 2-deoxy- d- arabino/ lyxo-hexopyranosyl disaccharides

Synthesis of 2-deoxy- d- arabino/ lyxo-hexopyranosyl disaccharides is reported. In these, the disaccharides contain 2-deoxy- arabino-hexopyranosyl and 2-deoxy- lyxo-hexopyranosyl sugars as either the reducing or the non-reducing or both the sugar units of the disaccharides. The activated 2-deoxy-1-t...

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Veröffentlicht in:Carbohydrate research 2008-02, Vol.343 (3), p.453-461
Hauptverfasser: Paul, Somak, Jayaraman, Narayanaswamy
Format: Artikel
Sprache:eng
Schlagworte:
Arabinose
Deoxy Sugars - chemical synthesis
Deoxysugars
Disaccharides - chemical synthesis
Glycals
Glycosylations
Pentoses
Thioglycosides
Thioglycosides - chemistry
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Zusammenfassung:Synthesis of 2-deoxy- d- arabino/ lyxo-hexopyranosyl disaccharides is reported. In these, the disaccharides contain 2-deoxy- arabino-hexopyranosyl and 2-deoxy- lyxo-hexopyranosyl sugars as either the reducing or the non-reducing or both the sugar units of the disaccharides. The activated 2-deoxy-1-thioglycosides served as the common precursors to prepare the 2-deoxy disaccharides with the above configurations.
ISSN:0008-6215
1873-426X
DOI:10.1016/j.carres.2007.11.017