1,2-Diphosphinobenzene as a synthon for the 1,2,3-triphospha- and 2-arsa-1,3-diphosphaindenyl anions and a stable organo derivative of the P8 unit of Hittorf's phosphorus
The electronic structure of the 1,2,3-triphosphaindenyl ligand suggests that it should exhibit enhanced pi-acceptor properties when compared to the eta(5)-indenyl system; this insight encouraged us to develop a simple synthetic pathway from 1,2-diphosphinobenzene to the 1,2,3-C(6)H(4)P(3) and 2-As-1...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2008-02 (7), p.856-858 |
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Hauptverfasser: | , , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The electronic structure of the 1,2,3-triphosphaindenyl ligand suggests that it should exhibit enhanced pi-acceptor properties when compared to the eta(5)-indenyl system; this insight encouraged us to develop a simple synthetic pathway from 1,2-diphosphinobenzene to the 1,2,3-C(6)H(4)P(3) and 2-As-1,3-C(6)H(4)P(2) anions, both of which have been structurally characterised by X-ray crystallography; as a bonus from these studies we also obtained the first structurally characterised organo derivative of the P(8) unit present in Hittorf's phosphorus. |
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ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/b717204d |