Dissociation Behavior of Clathrate Hydrates to Ice and Dependence on Guest Molecules

Dissociation Behavior of Clathrate Hydrates to Ice and Dependence on Guest Molecules

Self‐preservation: The existence of gas hydrates (see picture) outside their stability zone for prolonged periods is shown to depend on the interaction strength between guest molecules (red) and water (blue), as reflected by the dissociation pressures at 273 K.

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Veröffentlicht in:Angewandte Chemie (International ed.) 2008-02, Vol.47 (7), p.1276-1279
Hauptverfasser: Takeya, Satoshi, Ripmeester, John A
Format: Artikel
Sprache:eng
Schlagworte:
adsorption
clathrates
host-guest systems
hydrates
inclusion compounds
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Beschreibung
Zusammenfassung:Self‐preservation: The existence of gas hydrates (see picture) outside their stability zone for prolonged periods is shown to depend on the interaction strength between guest molecules (red) and water (blue), as reflected by the dissociation pressures at 273 K.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200703718