Formation of mesoscopic water networks in aqueous systems

Formation of the macroscopically-infinite hydrogen-bonded water network in various aqueous systems occurs via 3D percolation transition when the probability of finding a spanning water cluster exceeds 95%. As a result, in a wide interval of water content below the percolation threshold, rarefied qua...

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Veröffentlicht in:Physical chemistry chemical physics : PCCP 2007-01, Vol.9 (11), p.1341-1346
Hauptverfasser: PARTAY, Livia B, JEDLOVSZKY, Pal, BROVCHENKO, Ivan, OLEINIKOVA, Alla
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Sprache:eng
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Zusammenfassung:Formation of the macroscopically-infinite hydrogen-bonded water network in various aqueous systems occurs via 3D percolation transition when the probability of finding a spanning water cluster exceeds 95%. As a result, in a wide interval of water content below the percolation threshold, rarefied quasi-2D water networks span over the mesoscopic length scale. Formation and topology of spanning water networks, which affect various properties of aqueous systems, can be described within the framework of the percolation theory.
ISSN:1463-9076
1463-9084
DOI:10.1039/b617042k