Tuning Mechanism in a Two-Component Columnar Host System Composed of 1,2-Diphenylethylenediamine and 1,1‘-Binaphthyl-2,2‘-dicarboxylic Acid

Tuning Mechanism in a Two-Component Columnar Host System Composed of 1,2-Diphenylethylenediamine and 1,1‘-Binaphthyl-2,2‘-dicarboxylic Acid

In a two-component columnar host system composed of racemic (rac)-1,2-diphenylethylenediamine and rac-1,1‘-binaphthyl-2,2‘-dicarboxylic acid, a cavity tuning mechanism resulted from changes in the structure of the columns using a specific combination of the following four molecules:  (1R,2R)-1, (1S,...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Organic letters 2008-02, Vol.10 (3), p.469-471
Hauptverfasser: Imai, Yoshitane, Kawaguchi, Kakuhiro, Murata, Katuzo, Sato, Tomohiro, Kuroda, Reiko, Matsubara, Yoshio
Format: Artikel
Sprache:eng
Schlagworte:
Crystallography, X-Ray
Dicarboxylic Acids - chemistry
Ethylenediamines - chemistry
Molecular Conformation
Molecular Structure
Naphthalenes - chemistry
Stereoisomerism
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:In a two-component columnar host system composed of racemic (rac)-1,2-diphenylethylenediamine and rac-1,1‘-binaphthyl-2,2‘-dicarboxylic acid, a cavity tuning mechanism resulted from changes in the structure of the columns using a specific combination of the following four molecules:  (1R,2R)-1, (1S,2S)-1, (R)-2, and (S)-2.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol7028433