A New Versatile Strategy for C-Aryl Glycosides

A versatile strategy involving a sequential intermolecular enyne metathesis of C-alkynyl glycosides with ethylene, Diels−Alder, and aromatization reactions is successfully developed to provide a range of C-aryl glycosides.

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Veröffentlicht in:Organic letters 2007-03, Vol.9 (6), p.1121-1124
Hauptverfasser: Kaliappan, Krishna P, Subrahmanyam, Ayyagari V
Format: Artikel
Sprache:eng
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Zusammenfassung:A versatile strategy involving a sequential intermolecular enyne metathesis of C-alkynyl glycosides with ethylene, Diels−Alder, and aromatization reactions is successfully developed to provide a range of C-aryl glycosides.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol0701159