A stable zerovalent palladium chain enveloped by a pi-electron sheath of conjugated polyene ligands

A stable zerovalent palladium chain enveloped by a pi-electron sheath of conjugated polyene ligands

A surprisingly stable homoleptic Pd(0)(4) chain complex of non-activated olefins was isolated and structurally characterized by X-ray crystallographic analysis, and the unique structure and bonding are compared to those of the corresponding dicationic [Pd(4)](2+) chain sandwich complex.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2008-01 (4), p.477-479
Hauptverfasser: Tatsumi, Yasuki, Murahashi, Tetsuro, Okada, Mitsue, Ogoshi, Sensuke, Kurosawa, Hideo
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container_title Chemical communications (Cambridge, England)
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creator Tatsumi, Yasuki
Murahashi, Tetsuro
Okada, Mitsue
Ogoshi, Sensuke
Kurosawa, Hideo
description A surprisingly stable homoleptic Pd(0)(4) chain complex of non-activated olefins was isolated and structurally characterized by X-ray crystallographic analysis, and the unique structure and bonding are compared to those of the corresponding dicationic [Pd(4)](2+) chain sandwich complex.
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title A stable zerovalent palladium chain enveloped by a pi-electron sheath of conjugated polyene ligands
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