A stable zerovalent palladium chain enveloped by a pi-electron sheath of conjugated polyene ligands
A surprisingly stable homoleptic Pd(0)(4) chain complex of non-activated olefins was isolated and structurally characterized by X-ray crystallographic analysis, and the unique structure and bonding are compared to those of the corresponding dicationic [Pd(4)](2+) chain sandwich complex.
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2008-01 (4), p.477-479 |
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| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A surprisingly stable homoleptic Pd(0)(4) chain complex of non-activated olefins was isolated and structurally characterized by X-ray crystallographic analysis, and the unique structure and bonding are compared to those of the corresponding dicationic [Pd(4)](2+) chain sandwich complex. |
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| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/b714530f |