Structural characterization of Pu[N(SiMe(3))(2)](3), a synthetically useful nonaqueous plutonium(III) precursor

A rare, and synthetically versatile, nonaqueous plutonium complex, Pu[N(SiMe3)2]3 (1), has been structurally characterized by single-crystal X-ray diffraction for the first time and reveals significantly shorter agostic interactions compared to the cerium(III) analogue, indicating possible covalency...

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Veröffentlicht in:	Inorganic chemistry 2008-01, Vol.47 (1), p.26-28
Hauptverfasser:	Gaunt, Andrew J, Enriquez, Alejandro E, Reilly, Sean D, Scott, Brian L, Neu, Mary P
Format:	Artikel
Sprache:	eng
Schlagworte:	Crystallography, X-Ray Ligands Models, Molecular Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Organosilicon Compounds - chemistry Plutonium - chemistry
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description	A rare, and synthetically versatile, nonaqueous plutonium complex, Pu[N(SiMe3)2]3 (1), has been structurally characterized by single-crystal X-ray diffraction for the first time and reveals significantly shorter agostic interactions compared to the cerium(III) analogue, indicating possible covalency differences.
doi_str_mv	10.1021/ic701673e
format	Article
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subjects	Crystallography, X-Ray Ligands Models, Molecular Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Organosilicon Compounds - chemistry Plutonium - chemistry
title	Structural characterization of Pu[N(SiMe(3))(2)](3), a synthetically useful nonaqueous plutonium(III) precursor
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