Structural characterization of Pu[N(SiMe(3))(2)](3), a synthetically useful nonaqueous plutonium(III) precursor

Structural characterization of Pu[N(SiMe(3))(2)](3), a synthetically useful nonaqueous plutonium(III) precursor

A rare, and synthetically versatile, nonaqueous plutonium complex, Pu[N(SiMe3)2]3 (1), has been structurally characterized by single-crystal X-ray diffraction for the first time and reveals significantly shorter agostic interactions compared to the cerium(III) analogue, indicating possible covalency...

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Veröffentlicht in:Inorganic chemistry 2008-01, Vol.47 (1), p.26-28
Hauptverfasser: Gaunt, Andrew J, Enriquez, Alejandro E, Reilly, Sean D, Scott, Brian L, Neu, Mary P
Format: Artikel
Sprache:eng
Schlagworte:
Crystallography, X-Ray
Ligands
Models, Molecular
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Organosilicon Compounds - chemistry
Plutonium - chemistry
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Zusammenfassung:A rare, and synthetically versatile, nonaqueous plutonium complex, Pu[N(SiMe3)2]3 (1), has been structurally characterized by single-crystal X-ray diffraction for the first time and reveals significantly shorter agostic interactions compared to the cerium(III) analogue, indicating possible covalency differences.
ISSN:0020-1669
DOI:10.1021/ic701673e