A Tetrahedral Organophosphonate as a Linker for a Microporous Copper Framework

A Tetrahedral Organophosphonate as a Linker for a Microporous Copper Framework

Role reversal: A copper phosphonate network is synthesized using a ligand‐directed, rather than a cluster‐directed, approach. The doubly interpenetrated diamondoid framework (see space‐filling representation) contains accessible micropores, as demonstrated by CO2 sorption experiments.

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Veröffentlicht in:Angewandte Chemie International Edition 2007-01, Vol.46 (5), p.795-798
Hauptverfasser: Taylor, Jared M., Mahmoudkhani, Amir H., Shimizu, George K. H.
Format: Artikel
Sprache:eng
Schlagworte:
cluster compounds
copper
metal-organic frameworks
microporous materials
phosphonates
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Zusammenfassung:Role reversal: A copper phosphonate network is synthesized using a ligand‐directed, rather than a cluster‐directed, approach. The doubly interpenetrated diamondoid framework (see space‐filling representation) contains accessible micropores, as demonstrated by CO2 sorption experiments.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200604034