Surface-Assisted Assembly of 2D Metal-Organic Networks That Exhibit Unusual Threefold Coordination Symmetry

Surface-Assisted Assembly of 2D Metal-Organic Networks That Exhibit Unusual Threefold Coordination Symmetry

Independent symmetries characterize the evolving network and the metal surface on which the network forms in the surface‐assisted assembly of ligands and metal centers to 2D honeycomb networks comprising threefold coordination motifs (see picture, Co purple, N green). This type of coordination, whic...

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Veröffentlicht in:Angewandte Chemie International Edition 2007-01, Vol.46 (5), p.710-713
Hauptverfasser: Stepanow, Sebastian, Lin, Nian, Payer, Dietmar, Schlickum, Uta, Klappenberger, Florian, Zoppellaro, Giorgio, Ruben, Mario, Brune, Harald, Barth, Johannes V., Kern, Klaus
Format: Artikel
Sprache:eng
Schlagworte:
coordination modes
ligand effects
scanning probe microscopy
supramolecular chemistry
surface chemistry
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Beschreibung
Zusammenfassung:Independent symmetries characterize the evolving network and the metal surface on which the network forms in the surface‐assisted assembly of ligands and metal centers to 2D honeycomb networks comprising threefold coordination motifs (see picture, Co purple, N green). This type of coordination, which is rarely encountered in 3D metal–organic frameworks, is promoted by the strict confinement of a 2D environment.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200603644