Effect of copper metal on the yield of Sc3N@C80 metallofullerenes

Effect of copper metal on the yield of Sc3N@C80 metallofullerenes

The yield of Sc3N@C80 metallofullerene and fullerene extract is dramatically increased via filling cored graphite rods with copper and Sc2O3 only; when compared to 100% Sc2O3 packed rods, improvements of factors of approximately 3 and approximately 5 have been achieved for Sc3N@C80 and fullerene ext...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2007 (41), p.4263-4265
Hauptverfasser: Stevenson, Steven, Mackey, Mary A, Thompson, M Corey, Coumbe, H Louie, Madasu, Praveen K, Coumbe, Curtis E, Phillips, J Paige
Format: Artikel
Sprache:eng
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Zusammenfassung:The yield of Sc3N@C80 metallofullerene and fullerene extract is dramatically increased via filling cored graphite rods with copper and Sc2O3 only; when compared to 100% Sc2O3 packed rods, improvements of factors of approximately 3 and approximately 5 have been achieved for Sc3N@C80 and fullerene extract produced, respectively, with the weight percent of Cu added to the rod affecting the type and amount of fullerene produced.
ISSN:1359-7345
1364-548X
DOI:10.1039/b706859j