Functionalization of silicon surfaces with catalytically active Pd complexes and application to the aerobic oxidation of benzylic alcohols
A single-crystal silicon surface was modified with a bisoxazoline-Pd molecular layer and utilized as a highly efficient (catalyst turnover number up to 780,000, 110 degrees C, 72 h) and recyclable catalyst in the aerobic oxidation of benzylic alcohols.
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2007-01 (41), p.4280-4282 |
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| container_end_page | 4282 |
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| container_issue | 41 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Hara, Kenji Tayama, Shinobu Kano, Hidekazu Masuda, Takuya Takakusagi, Satoru Kondo, Toshihiro Uosaki, Kohei Sawamura, Masaya |
| description | A single-crystal silicon surface was modified with a bisoxazoline-Pd molecular layer and utilized as a highly efficient (catalyst turnover number up to 780,000, 110 degrees C, 72 h) and recyclable catalyst in the aerobic oxidation of benzylic alcohols. |
| doi_str_mv | 10.1039/b710820f |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2007-01 (41), p.4280-4282 |
| issn | 1359-7345 1364-548X |
| language | eng |
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| source | MEDLINE; Royal Society of Chemistry Journals Archive (1841-2007); Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Benzyl Alcohols - chemistry Catalysis Ketones - chemical synthesis Ketones - chemistry Molecular Structure Organometallic Compounds - chemistry Oxazoles - chemistry Oxidation-Reduction Oxygen - chemistry Palladium - chemistry Silicon - chemistry Surface Properties |
| title | Functionalization of silicon surfaces with catalytically active Pd complexes and application to the aerobic oxidation of benzylic alcohols |
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