Functionalization of silicon surfaces with catalytically active Pd complexes and application to the aerobic oxidation of benzylic alcohols

Functionalization of silicon surfaces with catalytically active Pd complexes and application to the aerobic oxidation of benzylic alcohols

A single-crystal silicon surface was modified with a bisoxazoline-Pd molecular layer and utilized as a highly efficient (catalyst turnover number up to 780,000, 110 degrees C, 72 h) and recyclable catalyst in the aerobic oxidation of benzylic alcohols.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2007-01 (41), p.4280-4282
Hauptverfasser: Hara, Kenji, Tayama, Shinobu, Kano, Hidekazu, Masuda, Takuya, Takakusagi, Satoru, Kondo, Toshihiro, Uosaki, Kohei, Sawamura, Masaya
Format: Artikel
Sprache:eng
Schlagworte:
Benzyl Alcohols - chemistry
Catalysis
Ketones - chemical synthesis
Ketones - chemistry
Molecular Structure
Organometallic Compounds - chemistry
Oxazoles - chemistry
Oxidation-Reduction
Oxygen - chemistry
Palladium - chemistry
Silicon - chemistry
Surface Properties
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Beschreibung
Zusammenfassung:A single-crystal silicon surface was modified with a bisoxazoline-Pd molecular layer and utilized as a highly efficient (catalyst turnover number up to 780,000, 110 degrees C, 72 h) and recyclable catalyst in the aerobic oxidation of benzylic alcohols.
ISSN:1359-7345
1364-548X
DOI:10.1039/b710820f