Mechanism of copper-catalyzed autoxidation of cysteine

The kinetics of copper-catalyzed autoxidation of cysteine and its derivatives were investigated using oxygen consumption, spectroscopy and hydroxyl radical detection by fluorescence of a coumarin probe. The process has complex two-phase kinetics. During the first phase a stoichiometric amount of oxy...

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Veröffentlicht in:Free radical research 1999-01, Vol.31 (1), p.23-34
Hauptverfasser: Kachur, Alexander V., Koch, Cameron J., Biaglow, John E.
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Sprache:eng
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