Impurity Nuclear Spin–Lattice Relaxation Suppression and Charge Exchange of Chromium Ions in a γ-Irradiated Ruby Crystal

The possibility of directly separating and measuring the impurity and lattice contributions to nuclear spin–lattice relaxation under the condition of a steady-state magnetic saturation is demonstrated in the particular case of27Al nuclei in a γ-irradiated ruby crystal. Contributions from trivalent a...

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Veröffentlicht in:Journal of magnetic resonance (1997) 1998-11, Vol.135 (1), p.113-117
Hauptverfasser: Chandoul, Ali, Charnaya, E.V., Kuleshov, A.A., Mikushev, V.M., Ulyashev, A.M.
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Sprache:eng
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Zusammenfassung:The possibility of directly separating and measuring the impurity and lattice contributions to nuclear spin–lattice relaxation under the condition of a steady-state magnetic saturation is demonstrated in the particular case of27Al nuclei in a γ-irradiated ruby crystal. Contributions from trivalent and charge-exchanged chromium ions to impurity nuclear relaxation were separated. The number of charge-exchanged chromium ions was found. The spin relaxation time of Cr4+centers was estimated.
ISSN:1090-7807
1096-0856
DOI:10.1006/jmre.1998.1550