Bis-Carbene Adducts of Non-IPR La₂@C₇₂: Localization of High Reactivity around Fused Pentagons and Electrochemical Properties

Bis-Carbene Adducts of Non-IPR La₂@C₇₂: Localization of High Reactivity around Fused Pentagons and Electrochemical Properties

Candylike fullerene: Two adamantylidene (Ad) groups are covalently bonded to the two fused‐pentagon sites of the non‐IPR endohedral metallofullerene La2@C72 in bis‐adduct La2@C72Ad2. Its open‐cage structure, reminiscent of a wrapped candy, was determined by single‐crystal X‐ray diffraction (see pict...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2008-10, Vol.47 (45), p.8642-8645
Hauptverfasser: Lu, Xing, Nikawa, Hidefumi, Tsuchiya, Takahiro, Maeda, Yutaka, Ishitsuka, Midori O, Akasaka, Takeshi, Toki, Makoto, Sawa, Hiroshi, Slanina, Zdenek, Mizorogi, Naomi, Nagase, Shigeru
Format: Artikel
Sprache:eng
Schlagworte:
carbenes
fullerenes
lanthanum
photochemistry
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Zusammenfassung:Candylike fullerene: Two adamantylidene (Ad) groups are covalently bonded to the two fused‐pentagon sites of the non‐IPR endohedral metallofullerene La2@C72 in bis‐adduct La2@C72Ad2. Its open‐cage structure, reminiscent of a wrapped candy, was determined by single‐crystal X‐ray diffraction (see picture), and it retains the electronic structure of pristine La2@C72.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200803529