Soluble Boron-Nitrogen High Polymers from Metal-Complex-Catalyzed Amine Borane Dehydrogenation

Taking the high road is what reactions of primary amine boranes do, according to results recently obtained by Manners and co‐workers, when a homogeneous catalyst is used to prepare soluble aminoborane polymers and copolymers (see scheme; pocop=ϰ3‐1,3‐(OPtBu2)2C6H3). Such metal‐catalyzed dehydrocoupl...

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Veröffentlicht in:	Angewandte Chemie (International ed.) 2008-12, Vol.47 (50), p.9600-9602
Hauptverfasser:	Pons, Vincent, Baker, R. Tom
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Sprache:	eng
Schlagworte:	boron dehydrocoupling homogeneous catalysis nitrogen polymers
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description	Taking the high road is what reactions of primary amine boranes do, according to results recently obtained by Manners and co‐workers, when a homogeneous catalyst is used to prepare soluble aminoborane polymers and copolymers (see scheme; pocop=ϰ3‐1,3‐(OPtBu2)2C6H3). Such metal‐catalyzed dehydrocoupling reactions for the synthesis of new BN analogues of α‐olefins are of fundamental interest for materials science.
doi_str_mv	10.1002/anie.200803089
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Tom</creatorcontrib><title>Soluble Boron-Nitrogen High Polymers from Metal-Complex-Catalyzed Amine Borane Dehydrogenation</title><title>Angewandte Chemie (International ed.)</title><addtitle>Angewandte Chemie International Edition</addtitle><description>Taking the high road is what reactions of primary amine boranes do, according to results recently obtained by Manners and co‐workers, when a homogeneous catalyst is used to prepare soluble aminoborane polymers and copolymers (see scheme; pocop=ϰ3‐1,3‐(OPtBu2)2C6H3). 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title	Soluble Boron-Nitrogen High Polymers from Metal-Complex-Catalyzed Amine Borane Dehydrogenation
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