Soluble Boron-Nitrogen High Polymers from Metal-Complex-Catalyzed Amine Borane Dehydrogenation

Soluble Boron-Nitrogen High Polymers from Metal-Complex-Catalyzed Amine Borane Dehydrogenation

Taking the high road is what reactions of primary amine boranes do, according to results recently obtained by Manners and co‐workers, when a homogeneous catalyst is used to prepare soluble aminoborane polymers and copolymers (see scheme; pocop=ϰ3‐1,3‐(OPtBu2)2C6H3). Such metal‐catalyzed dehydrocoupl...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2008-12, Vol.47 (50), p.9600-9602
Hauptverfasser: Pons, Vincent, Baker, R. Tom
Format: Artikel
Sprache:eng
Schlagworte:
boron
dehydrocoupling
homogeneous catalysis
nitrogen
polymers
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Beschreibung
Zusammenfassung:Taking the high road is what reactions of primary amine boranes do, according to results recently obtained by Manners and co‐workers, when a homogeneous catalyst is used to prepare soluble aminoborane polymers and copolymers (see scheme; pocop=ϰ3‐1,3‐(OPtBu2)2C6H3). Such metal‐catalyzed dehydrocoupling reactions for the synthesis of new BN analogues of α‐olefins are of fundamental interest for materials science.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200803089