The doping effect of fluorinated aromatic hydrocarbon solvents on the performance of common olefin metathesis catalysts: application in the preparation of biologically active compounds

The doping effect of fluorinated aromatic hydrocarbon solvents on the performance of common olefin metathesis catalysts: application in the preparation of biologically active compounds

Aromatic fluorinated hydrocarbons, used as solvents for olefin metathesis reactions, catalysed by standard commercially available Ru precatalysts, allow substantially higher yields to be obtained, especially of challenging substrates, including natural and biologically active compounds.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2008-01 (47), p.6282-6284
Hauptverfasser: Samojłowicz, Cezary, Bieniek, Michał, Zarecki, Andrzej, Kadyrov, Renat, Grela, Karol
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes - chemistry
Biological Products - chemical synthesis
Biological Products - chemistry
Biology
Catalysis
Fluorine Compounds - chemistry
Hydrocarbons, Aromatic - chemistry
Magnetic Resonance Spectroscopy
Molecular Structure
Solvents - chemistry
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Beschreibung
Zusammenfassung:Aromatic fluorinated hydrocarbons, used as solvents for olefin metathesis reactions, catalysed by standard commercially available Ru precatalysts, allow substantially higher yields to be obtained, especially of challenging substrates, including natural and biologically active compounds.
ISSN:1359-7345
1364-548X
DOI:10.1039/b816567j