Self‐Assembly of a Heteropolyoxopalladate Nanocube: [PdII13AsV8O34(OH)6]8
Not like the others: A molecular palladium oxide cluster was formed by self‐assembly of palladium(II) and arsenic(V) using mild reaction conditions. The resulting heteropolypalladate [PdII13AsV8O34(OH)6]8− has a distorted cubic shape and edge lengths of about 1 nm. The thirteen PdII ions retain four...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2008-11, Vol.47 (49), p.9542-9546 |
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| container_issue | 49 |
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| container_title | Angewandte Chemie International Edition |
| container_volume | 47 |
| creator | Chubarova, Elena V. Dickman, Michael H. Keita, Bineta Nadjo, Louis Miserque, Frédéric Mifsud, Maria Arends, Isabel W. C. E. Kortz, Ulrich |
| description | Not like the others: A molecular palladium oxide cluster was formed by self‐assembly of palladium(II) and arsenic(V) using mild reaction conditions. The resulting heteropolypalladate [PdII13AsV8O34(OH)6]8− has a distorted cubic shape and edge lengths of about 1 nm. The thirteen PdII ions retain four‐coordinate square‐planar geometry, in marked contrast to all other known discrete polyoxometalates. |
| doi_str_mv | 10.1002/anie.200803527 |
| format | Article |
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The thirteen PdII ions retain four‐coordinate square‐planar geometry, in marked contrast to all other known discrete polyoxometalates.</description><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.200803527</identifier><identifier>PMID: 18850625</identifier><language>eng</language><publisher>Weinheim: WILEY‐VCH Verlag</publisher><subject>Arsenates - chemistry ; Arsenic - chemistry ; electrochemistry ; Molecular Conformation ; nanoclusters ; Nanoparticles - chemistry ; oxidation catalysis ; palladium ; Palladium - chemistry ; Particle Size ; polyoxometalates ; Tungsten Compounds - chemistry</subject><ispartof>Angewandte Chemie International Edition, 2008-11, Vol.47 (49), p.9542-9546</ispartof><rights>Copyright © 2008 WILEY‐VCH Verlag GmbH & Co. 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The thirteen PdII ions retain four‐coordinate square‐planar geometry, in marked contrast to all other known discrete polyoxometalates.</description><subject>Arsenates - chemistry</subject><subject>Arsenic - chemistry</subject><subject>electrochemistry</subject><subject>Molecular Conformation</subject><subject>nanoclusters</subject><subject>Nanoparticles - chemistry</subject><subject>oxidation catalysis</subject><subject>palladium</subject><subject>Palladium - chemistry</subject><subject>Particle Size</subject><subject>polyoxometalates</subject><subject>Tungsten Compounds - chemistry</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkMtKw0AUQAdRbK1uXUpWoovUmUzmEXehVBssreBjIzJMMjcQSTo106DZ-Ql-o19iSotdurp3ce7hchA6JXhIMA6u9KKAYYCxxJQFYg_1CQuIT4Wg-90eUuoLyUgPHTn31vFSYn6IekRKhnnA-ujuAcr85-s7dg6qtGw9m3vam8AKaru0ZWs_7VKXpTZ6Bd5ML2zWpHDtvdybJCE0ds9yTsOL-eSSv8pjdJDr0sHJdg7Q0834cTTxp_PbZBRP_SxgofBTERmKhdY8pJnkFBvJGYVMU5nJNNCcCx0RHkpNOBac6NwQZiAkjLLcCKADdL7xLmv73oBbqapwGXRfLsA2TvFIBoIS2YHDDZjV1rkacrWsi0rXrSJYrfOpdT71l687ONuam7QCs8O3vTog2gAfRQntPzoVz5LxTv4LJAx6gw</recordid><startdate>20081124</startdate><enddate>20081124</enddate><creator>Chubarova, Elena V.</creator><creator>Dickman, Michael H.</creator><creator>Keita, Bineta</creator><creator>Nadjo, Louis</creator><creator>Miserque, Frédéric</creator><creator>Mifsud, Maria</creator><creator>Arends, Isabel W. 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| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie International Edition, 2008-11, Vol.47 (49), p.9542-9546 |
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| source | MEDLINE; Wiley Online Library Journals Frontfile Complete |
| subjects | Arsenates - chemistry Arsenic - chemistry electrochemistry Molecular Conformation nanoclusters Nanoparticles - chemistry oxidation catalysis palladium Palladium - chemistry Particle Size polyoxometalates Tungsten Compounds - chemistry |
| title | Self‐Assembly of a Heteropolyoxopalladate Nanocube: [PdII13AsV8O34(OH)6]8 |
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