Self‐Assembly of a Heteropolyoxopalladate Nanocube: [PdII13AsV8O34(OH)6]8

Self‐Assembly of a Heteropolyoxopalladate Nanocube: [PdII13AsV8O34(OH)6]8

Not like the others: A molecular palladium oxide cluster was formed by self‐assembly of palladium(II) and arsenic(V) using mild reaction conditions. The resulting heteropolypalladate [PdII13AsV8O34(OH)6]8− has a distorted cubic shape and edge lengths of about 1 nm. The thirteen PdII ions retain four...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 2008-11, Vol.47 (49), p.9542-9546
Hauptverfasser: Chubarova, Elena V., Dickman, Michael H., Keita, Bineta, Nadjo, Louis, Miserque, Frédéric, Mifsud, Maria, Arends, Isabel W. C. E., Kortz, Ulrich
Format: Artikel
Sprache:eng
Schlagworte:
Arsenates - chemistry
Arsenic - chemistry
electrochemistry
Molecular Conformation
nanoclusters
Nanoparticles - chemistry
oxidation catalysis
palladium
Palladium - chemistry
Particle Size
polyoxometalates
Tungsten Compounds - chemistry
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Not like the others: A molecular palladium oxide cluster was formed by self‐assembly of palladium(II) and arsenic(V) using mild reaction conditions. The resulting heteropolypalladate [PdII13AsV8O34(OH)6]8− has a distorted cubic shape and edge lengths of about 1 nm. The thirteen PdII ions retain four‐coordinate square‐planar geometry, in marked contrast to all other known discrete polyoxometalates.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200803527