Unusual face-to-face pi-pi stacking interactions within an indigo-pillared M3(tpt)-based triangular metalloprism

Unusual face-to-face pi-pi stacking interactions within an indigo-pillared M3(tpt)-based triangular metalloprism

A triangular metalloprism, [((CO)3Re(mu-2)Re(CO)3)3(mu3-1)2], self-assembled from Re2(CO)10, 2,4,6-tri-4-pyridyl-1,3,5-triazine (tpt, 1), and indigo (H2(2)), represents a fairly novel example of strong face-to-face pi-pi interactions between the central triazine rings of the tpt ligands that bow sig...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2008-11 (44), p.6110-6112
Hauptverfasser: Wu, Jing-Yun, Chang, Che-Hao, Thanasekaran, P, Tsai, Chen-Chuan, Tseng, Tien-Wen, Lee, Gene-Hsiang, Peng, Shie-Ming, Lu, Kuang-Lieh
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Sprache:eng
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Zusammenfassung:A triangular metalloprism, [((CO)3Re(mu-2)Re(CO)3)3(mu3-1)2], self-assembled from Re2(CO)10, 2,4,6-tri-4-pyridyl-1,3,5-triazine (tpt, 1), and indigo (H2(2)), represents a fairly novel example of strong face-to-face pi-pi interactions between the central triazine rings of the tpt ligands that bow significantly inward distorting the prismatic structure.
ISSN:1477-9226
1477-9234
DOI:10.1039/b809489f