Bis-Tris Propane as a New Polydentate Linker in the Synthesis of Iron(III) and Manganese(II/III) Complexes

Bis-Tris Propane as a New Polydentate Linker in the Synthesis of Iron(III) and Manganese(II/III) Complexes

We describe the synthesis, structure, and magnetic properties of two new complexes, one decanuclear iron(III) cluster and one hexanuclear mixed-valence manganese(II/III) cluster, where the previously unexplored polydentate ligand Bis-tris propane {(CH2OH)3CNH(CH2)3NHC(CH2OH)3} is used to link small...

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Veröffentlicht in:Inorganic chemistry 2008-11, Vol.47 (21), p.9742-9744
Hauptverfasser: Ferguson, Alan, Darwish, Amiera, Graham, Kristoffer, Schmidtmann, Marc, Parkin, Andrew, Murrie, Mark
Format: Artikel
Sprache:eng
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Zusammenfassung:We describe the synthesis, structure, and magnetic properties of two new complexes, one decanuclear iron(III) cluster and one hexanuclear mixed-valence manganese(II/III) cluster, where the previously unexplored polydentate ligand Bis-tris propane {(CH2OH)3CNH(CH2)3NHC(CH2OH)3} is used to link small cluster fragments into high-nuclearity complexes.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic8015386