Immobilization Method of Chiral Quaternary Ammonium Salts onto Polymer Supports

Direct support: The title compounds have been used as polymeric organocatalysts (see structure) in the asymmetric alkylation of a glycine derivative to give the corresponding phenylalanine with high enantioselectivity. The polymeric catalyst can be reused without loss of its catalytic activity.

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Veröffentlicht in:Angewandte Chemie (International ed.) 2008-10, Vol.47 (43), p.8232-8235
Hauptverfasser: Arakawa, Yukihiro, Haraguchi, Naoki, Itsuno, Shinichi
Format: Artikel
Sprache:eng
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Zusammenfassung:Direct support: The title compounds have been used as polymeric organocatalysts (see structure) in the asymmetric alkylation of a glycine derivative to give the corresponding phenylalanine with high enantioselectivity. The polymeric catalyst can be reused without loss of its catalytic activity.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200802800