Supported Silver-Nanoparticle-Catalyzed Highly Efficient Aqueous Oxidation of Phenylsilanes to Silanols

Bon Apatite! Hydroxyapatite‐supported silver nanoparticles act as a highly efficient heterogeneous catalyst for the oxidation of diverse phenylsilanes into silanols in water (see picture; C orange, H red, O blue, R purple, Si green), while suppressing significant condensation to the disiloxanes. The...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2008-09, Vol.47 (41), p.7938-7940
Hauptverfasser: Mitsudome, Takato, Arita, Shusuke, Mori, Haruhiko, Mizugaki, Tomoo, Jitsukawa, Koichiro, Kaneda, Kiyotomi
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Sprache:eng
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Zusammenfassung:Bon Apatite! Hydroxyapatite‐supported silver nanoparticles act as a highly efficient heterogeneous catalyst for the oxidation of diverse phenylsilanes into silanols in water (see picture; C orange, H red, O blue, R purple, Si green), while suppressing significant condensation to the disiloxanes. The solid silver catalyst is readily reusable without any loss of activity or selectivity.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200802761