Supported Silver-Nanoparticle-Catalyzed Highly Efficient Aqueous Oxidation of Phenylsilanes to Silanols
Bon Apatite! Hydroxyapatite‐supported silver nanoparticles act as a highly efficient heterogeneous catalyst for the oxidation of diverse phenylsilanes into silanols in water (see picture; C orange, H red, O blue, R purple, Si green), while suppressing significant condensation to the disiloxanes. The...
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Veröffentlicht in: | Angewandte Chemie (International ed.) 2008-09, Vol.47 (41), p.7938-7940 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Bon Apatite! Hydroxyapatite‐supported silver nanoparticles act as a highly efficient heterogeneous catalyst for the oxidation of diverse phenylsilanes into silanols in water (see picture; C orange, H red, O blue, R purple, Si green), while suppressing significant condensation to the disiloxanes. The solid silver catalyst is readily reusable without any loss of activity or selectivity. |
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ISSN: | 1433-7851 1521-3773 |
DOI: | 10.1002/anie.200802761 |