Metal Complexes of Aminyl Radicals

Metal Complexes of Aminyl Radicals

Innocent until proven …︁ non‐innocent! Until recently, metal complexes of neutral aminyl radicals have proven very elusive in comparison to the more common metal amide valence isomer. Recent publications are discussed in which the synthesis and elucidation of genuine, isolable metal aminyl radical c...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2008-09, Vol.47 (39), p.7393-7395
1. Verfasser: Hicks, Robin G
Format: Artikel
Sprache:eng
Schlagworte:
electronic structure
N ligands
nitrogen
radicals
transition metals
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Zusammenfassung:Innocent until proven …︁ non‐innocent! Until recently, metal complexes of neutral aminyl radicals have proven very elusive in comparison to the more common metal amide valence isomer. Recent publications are discussed in which the synthesis and elucidation of genuine, isolable metal aminyl radical complexes have been realized.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200802713