Total Synthesis of (±)-Biphyscion

A regiospecific total synthesis of (±)-biphyscion (1) is described. A novel aspect of the plan was construction of the bianthraquinone ring system from a biphenyl intermediate through the use of a one-pot, double isobenzofuranone condensation.

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Veröffentlicht in:Organic letters 1999-08, Vol.1 (4), p.671-672
Hauptverfasser: Hauser, Frank M, Gauuan, Polivina Jolicia F
Format: Artikel
Sprache:eng
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Zusammenfassung:A regiospecific total synthesis of (±)-biphyscion (1) is described. A novel aspect of the plan was construction of the bianthraquinone ring system from a biphenyl intermediate through the use of a one-pot, double isobenzofuranone condensation.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol990758r