Self-Sorting Organization of Two Heteroditopic Monomers to Supramolecular Alternating Copolymers

Self-Sorting Organization of Two Heteroditopic Monomers to Supramolecular Alternating Copolymers

Self-sorting organization of two AB-type heteroditopic monomers led to the formation of linear supramolecular alternating copolymers driven by host−guest noncovalent interactions based on the bis(p-phenylene)-34-crown-10/paraquat derivative and dibenzo-24-crown-8/dibenzylammonium salt recognition mo...

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Veröffentlicht in:Journal of the American Chemical Society 2008-08, Vol.130 (34), p.11254-11255
Hauptverfasser: Wang, Feng, Han, Chenyou, He, Chunlin, Zhou, Qizhong, Zhang, Jinqiang, Wang, Cong, Li, Ning, Huang, Feihe
Format: Artikel
Sprache:eng
Schlagworte:
Electrochemistry
Heterocyclic Compounds - chemistry
Magnetic Resonance Spectroscopy
Microscopy, Electron, Scanning
Models, Chemical
Polymers - chemical synthesis
Scattering, Radiation
Viscosity
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Zusammenfassung:Self-sorting organization of two AB-type heteroditopic monomers led to the formation of linear supramolecular alternating copolymers driven by host−guest noncovalent interactions based on the bis(p-phenylene)-34-crown-10/paraquat derivative and dibenzo-24-crown-8/dibenzylammonium salt recognition motifs as confirmed by 1H NMR, cyclic voltammetry, dynamic light scattering, viscosity measurements, and scanning electron microscopy.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja8035465