Magnesium Nitride as a Convenient Source of Ammonia: Preparation of Dihydropyridines

Magnesium Nitride as a Convenient Source of Ammonia: Preparation of Dihydropyridines

Magnesium nitride (Mg3N2) has been investigated for the preparation of dihydropyridines. This is a commercially available, bench-stable solid that generates ammonia upon treatment with protic solvents. The main features of the process are the facile reaction setup and good yields obtained in the maj...

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Veröffentlicht in:Organic letters 2008-08, Vol.10 (16), p.3627-3629
Hauptverfasser: Bridgwood, Katy L, Veitch, Gemma E, Ley, Steven V
Format: Artikel
Sprache:eng
Schlagworte:
Aldehydes - chemistry
Ammonia - chemical synthesis
Ammonia - chemistry
Dihydropyridines - chemical synthesis
Dihydropyridines - chemistry
Esters - chemistry
Magnesium Compounds - chemistry
Molecular Structure
Stereoisomerism
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Zusammenfassung:Magnesium nitride (Mg3N2) has been investigated for the preparation of dihydropyridines. This is a commercially available, bench-stable solid that generates ammonia upon treatment with protic solvents. The main features of the process are the facile reaction setup and good yields obtained in the majority of cases.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol801399w