Copper-Mediated C−H Bond Arylation of Arenes with Arylboronic Acids

A new copper-mediated cross-coupling of arenes and arylboronic acids is described. Under the influence of Cu(OCOCF3)2, the C−H bond arylation of electron-rich arenes with arylboronic acids takes place to afford a range of biaryls in good yields. The reaction is selective for cross-coupling; no homoc...

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Veröffentlicht in:	Organic letters 2008-08, Vol.10 (16), p.3607-3609
Hauptverfasser:	Ban, Ikuya, Sudo, Tomoko, Taniguchi, Tadashi, Itami, Kenichiro
Format:	Artikel
Sprache:	eng
Schlagworte:	Boronic Acids - chemistry Copper - chemistry Hydrocarbons, Aromatic - chemical synthesis Hydrocarbons, Aromatic - chemistry Molecular Structure Organometallic Compounds - chemistry Stereoisomerism
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