Nucleation of Calcium Carbonate as Polymorphic Crystals in the Presence of Lipid A-Diphosphate
The well-defined structure of lipid A-diphosphate in aqueous solutions provides a way of observing the formation of calcium carbonate crystals. The crystals are either tetrahedral or rhombohedral calcite at a volume fraction of ϕ = 5.4 × 10−4 at pH 5.8 or the vaterite polymorph of CaCO3 at a volume...
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| Veröffentlicht in: | The journal of physical chemistry. B 2008-07, Vol.112 (30), p.8859-8862 |
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| container_title | The journal of physical chemistry. B |
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| creator | Faunce, Chester A Reichelt, Hendrik Paradies, Henrich H |
| description | The well-defined structure of lipid A-diphosphate in aqueous solutions provides a way of observing the formation of calcium carbonate crystals. The crystals are either tetrahedral or rhombohedral calcite at a volume fraction of ϕ = 5.4 × 10−4 at pH 5.8 or the vaterite polymorph of CaCO3 at a volume fraction of ϕ = 7.8 × 10−4 at pH 5.8. In both cases, nucleation, adsorption pH, and the shape-dependent template of lipid A-diphosphate control the formation of the calcite and vaterite. |
| doi_str_mv | 10.1021/jp803067b |
| format | Article |
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| subjects | Calcium Carbonate - chemistry Crystallization Lipid A - analogs & derivatives Lipid A - chemistry Microscopy, Electron, Scanning |
| title | Nucleation of Calcium Carbonate as Polymorphic Crystals in the Presence of Lipid A-Diphosphate |
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