Formation of titanacyclobutenes with a spiro-bonded cyclopropane
The reaction of titanium cyclopropylidene complexes, prepared by the reductive titanation of 7,7-dichlorobicyclo[4.1.0]heptanes, with alkynes produced air and moisture stable titanacyclobutenes with a spiro-bonded cyclopropane.
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2008-01 (30), p.3537-3539 |
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| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The reaction of titanium cyclopropylidene complexes, prepared by the reductive titanation of 7,7-dichlorobicyclo[4.1.0]heptanes, with alkynes produced air and moisture stable titanacyclobutenes with a spiro-bonded cyclopropane. |
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| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/b804930k |