Magnetostructural Study of 2-(4-N-tert-Butylaminoxylphenyl)benzimidazole

The heat capacity of the title organic free radical, PhBABI, was measured over 0.3−300 K by adiabatic calorimetry and relaxation methods in the presence of external magnetic fields up to 9 T. A hump in the magnetic heat capacity was observed with a maximum at about 15 K in zero field, which did not shift at fields up to 9 T. The experimental magnetic entropy was in good agreement with the theoretical value of R ln 2 (= 5.76 J K−1 mol−1) for S = 1/2 systems. The higher temperature, field-insensitive feature was fitted to several antiferromagnetic Heisenberg models. The best fits were obtained using spin ladder and coupled spin bilayer models.