Hysteretic sorption of light gases by a porous metal-organic framework containing tris(para-carboxylated) triphenylphosphine oxide

Hysteretic sorption of light gases by a porous metal-organic framework containing tris(para-carboxylated) triphenylphosphine oxide

The porous metal-organic framework (MOF) PCM-4, based on tris(para-carboxylated) triphenylphosphine oxide, contains atypical, polar organic substituents; the material exhibits a hysteretic sorption of Ar, N2 and O2, and demonstrates the advantage of ligands of this type.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2008-01 (25), p.2891-2893
Hauptverfasser: Humphrey, Simon M, Oungoulian, Shaunt E, Yoon, Ji Woong, Hwang, Young Kyu, Wise, Erica R, Chang, Jong-San
Format: Artikel
Sprache:eng
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Zusammenfassung:The porous metal-organic framework (MOF) PCM-4, based on tris(para-carboxylated) triphenylphosphine oxide, contains atypical, polar organic substituents; the material exhibits a hysteretic sorption of Ar, N2 and O2, and demonstrates the advantage of ligands of this type.
ISSN:1359-7345
1364-548X
DOI:10.1039/b802809e