Spectroscopic studies of zinc(II)tetraphenylporphyrin molecular complex with 1,4-dioxane

Spectroscopic studies of zinc(II)tetraphenylporphyrin molecular complex with 1,4-dioxane

The molecular complex of zinc(II)tetraphenylporphyrin with 1,4-dioxane has been obtained. The IR spectra of the [Zn(TPhP)(1,4-dioxane) 2] stabile molecular complex between 4000 and 50 cm −1 have been studied. An interpretation is given on the base the “chair” conformation of 1,4-dioxane molecule....

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Veröffentlicht in:Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy Molecular and biomolecular spectroscopy, 2008-09, Vol.70 (4), p.939-942
Hauptverfasser: Lebedeva, N.Sh, Karelin, A.I., Pavlycheva, N.A., Zielenkiewicz, W., Swierzewski, R.
Format: Artikel
Sprache:eng
Schlagworte:
Dioxanes - chemistry
DSC
FT-IR spectroscopy
Metalloporphyrin
Metalloporphyrins - chemistry
Molecular complex
Molecular Structure
Spectrophotometry, Infrared
Thermogravimetry
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Zusammenfassung:The molecular complex of zinc(II)tetraphenylporphyrin with 1,4-dioxane has been obtained. The IR spectra of the [Zn(TPhP)(1,4-dioxane) 2] stabile molecular complex between 4000 and 50 cm −1 have been studied. An interpretation is given on the base the “chair” conformation of 1,4-dioxane molecule.
ISSN:1386-1425
DOI:10.1016/j.saa.2008.01.007