Designed Synthesis of POM-Organic Frameworks from {Ni₆PW₉} Building Blocks under Hydrothermal Conditions

Designed Synthesis of POM-Organic Frameworks from {Ni₆PW₉} Building Blocks under Hydrothermal Conditions

Directed combination of {Ni6PW9} building blocks with various rigid carboxylate linkers under hydrothermal conditions yields a series of unprecedented polyoxometalate–organic frameworks (POMOFs) with remarkable structural diversity including 1D, 2D, and 3D structures based on monomers, dimers, or in...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2008-05, Vol.47 (21), p.3909-3913
Hauptverfasser: Zheng, Shou-Tian, Zhang, Jie, Yang, Guo-Yu
Format: Artikel
Sprache:eng
Schlagworte:
carboxylate ligands
hydrothermal synthesis
organic-inorganic hybrid composites
polyoxometalates
porous materials
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Zusammenfassung:Directed combination of {Ni6PW9} building blocks with various rigid carboxylate linkers under hydrothermal conditions yields a series of unprecedented polyoxometalate–organic frameworks (POMOFs) with remarkable structural diversity including 1D, 2D, and 3D structures based on monomers, dimers, or infinite helical chains (see picture for 3D structure: WO6: red; NiO6: green; PO4: yellow; 1,2,4‐benzenetricarboxylate: gold).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200705709