Syntheses of two enantiomeric pairs of myo-inositol(1,2,4,5,6) and -(1,2,3,4,5) pentakisphosphate

Two enantiomeric pairs of myo-inositol(1,2,4,5,6) P 5 and -(1,2,3,4,5) P 5 have efficiently been synthesized by means of the lipase catalyzed acetylation of 1,2:5,6-di- O-isopropylidene- myo-inositol and the benzoyl migration procedure. Two enantiomeric pairs of myo- inositol-(1,2, 4,5,6)P 5 and -(1...

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Veröffentlicht in:	Bioorganic & medicinal chemistry letters 1998-06, Vol.8 (12), p.1503-1506
Hauptverfasser:	Chung, Sung-Kee, Chang, Young-Tae, Lee, Eun Jung, Shin, Boo-Gyo, Kwon, Yong-Uk, Kim, Kyung-Cheol, Lee, Dong Hyun, Kim, Mahn-Joo
Format:	Artikel
Sprache:	eng
Schlagworte:	Bioconversions. Hemisynthesis Biological and medical sciences Biotechnology Carbohydrates with 4, 5, 6, ... C atoms, dissacharides and oligosaccharides Carbohydrates. Nucleosides and nucleotides Chemistry Exact sciences and technology Fundamental and applied biological sciences. Psychology Inositol Phosphates - chemical synthesis Inositol Phosphates - chemistry Methods. Procedures. Technologies Organic chemistry Preparations and properties Stereoisomerism
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Zusammenfassung:	Two enantiomeric pairs of myo-inositol(1,2,4,5,6) P 5 and -(1,2,3,4,5) P 5 have efficiently been synthesized by means of the lipase catalyzed acetylation of 1,2:5,6-di- O-isopropylidene- myo-inositol and the benzoyl migration procedure. Two enantiomeric pairs of myo- inositol-(1,2, 4,5,6)P 5 and -(1,2,3, 4,5)P 5 have efficiently been synthesized by means of the lipase catalyzed acetylation of 1,2:5,6-di- O-isopropylidene- myo-inositol and the benzoyl migration procedure.
ISSN:	0960-894X 1464-3405
DOI:	10.1016/S0960-894X(98)00245-5