Decarboxylative reduction of free aliphatic carboxylic acids by photogenerated cation radical

The decarboxylation of free carboxylic acids was effected by a photogenerated cation radical of phenanthrene to yield the reduction product in the presence of a thiol, which provides an alternative method to the Barton decarboxylation procedure for aliphatic acids such as N-Boc amino acids.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2007-01 (48), p.5244-5246
Hauptverfasser:	Yoshimi, Yasuharu, Itou, Tatsuya, Hatanaka, Minoru
Format:	Artikel
Sprache:	eng
Schlagworte:	Carboxylic Acids - chemistry Carboxylic Acids - radiation effects Cations - chemistry Cations - radiation effects Decarboxylation Free Radicals - chemical synthesis Free Radicals - chemistry Free Radicals - radiation effects Molecular Structure Organic Chemicals - chemical synthesis Organic Chemicals - chemistry Organic Chemicals - radiation effects Oxidation-Reduction Photochemistry Stereoisomerism Sulfhydryl Compounds - chemistry Ultraviolet Rays
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Beschreibung
Zusammenfassung:	The decarboxylation of free carboxylic acids was effected by a photogenerated cation radical of phenanthrene to yield the reduction product in the presence of a thiol, which provides an alternative method to the Barton decarboxylation procedure for aliphatic acids such as N-Boc amino acids.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/b714526h