A tetradecanuclear copper dimeric macrocyclic complex with a body-centred heptanuclear core-structure and magnetism
2,6-Diformyl-4-methylphenol and 1,3-diamino-2-hydroxypropane template condense in the presence of Cu(NO(3))(2) and azide to produce a 3 : 3 macrocyclic ring containing an unprecedented grouping of seven copper(ii) ions within the macrocyclic cavity, with the seventh metal completing a body-centred h...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2007-01 (8), p.798-800 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | 2,6-Diformyl-4-methylphenol and 1,3-diamino-2-hydroxypropane template condense in the presence of Cu(NO(3))(2) and azide to produce a 3 : 3 macrocyclic ring containing an unprecedented grouping of seven copper(ii) ions within the macrocyclic cavity, with the seventh metal completing a body-centred heptanuclear lattice. |
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| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/b612795a |