Rationally Designed Micropores within a Metal−Organic Framework for Selective Sorption of Gas Molecules

Rationally Designed Micropores within a Metal−Organic Framework for Selective Sorption of Gas Molecules

A microporous metal−organic framework, MOF, Cu(FMA)(4,4'-Bpe)0.5 (3a, FMA = fumarate; 4,4'-Bpe = 4,4’-Bpe = trans-bis(4-pyridyl)ethylene) was rationally designed from a primitive cubic net whose pores are tuned by double framework interpenetration. With pore cavities of about 3.6 Å, which...

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Veröffentlicht in:Inorganic chemistry 2007-02, Vol.46 (4), p.1233-1236
Hauptverfasser: Chen, Banglin, Ma, Shengqian, Zapata, Fatima, Fronczek, Frank R, Lobkovsky, Emil B, Zhou, Hong-Cai
Format: Artikel
Sprache:eng
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Zusammenfassung:A microporous metal−organic framework, MOF, Cu(FMA)(4,4'-Bpe)0.5 (3a, FMA = fumarate; 4,4'-Bpe = 4,4’-Bpe = trans-bis(4-pyridyl)ethylene) was rationally designed from a primitive cubic net whose pores are tuned by double framework interpenetration. With pore cavities of about 3.6 Å, which are interconnected by pore windows of 2.0 × 3.2 Å, 3a shows highly selective sorption behaviors of gas molecules.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic0616434