Domino Carbocationic Rearrangement of α-[Bis(methylthio)methylene]alkyl-2-(3/2-indolyl) Cyclopropyl Ketones

Domino carbocationic rearrangement of a number of substituted 3- and 2-indolylcyclopropyl ketones with an α-bis(methylthio)methylene group in the presence of various protic/Lewis acids yields a variety of products, mainly the pentaleno fused indoles and the carbazole derivatives.

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Bibliographische Detailangaben
Veröffentlicht in:	Journal of organic chemistry 2007-02, Vol.72 (4), p.1388-1394
Hauptverfasser:	Yadav, A. K, Peruncheralathan, S, Ila, H, Junjappa, H
Format:	Artikel
Sprache:	eng
Schlagworte:	Alicyclic compounds Alicyclic compounds, terpenoids, prostaglandins, steroids Chemistry Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with only one n hetero atom and condensed derivatives Organic chemistry Preparations and properties
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Beschreibung
Zusammenfassung:	Domino carbocationic rearrangement of a number of substituted 3- and 2-indolylcyclopropyl ketones with an α-bis(methylthio)methylene group in the presence of various protic/Lewis acids yields a variety of products, mainly the pentaleno fused indoles and the carbazole derivatives.
ISSN:	0022-3263 1520-6904
DOI:	10.1021/jo062302a