Structurally Characterized Quadruple-Stranded Bisbidentate Helicates

Structurally Characterized Quadruple-Stranded Bisbidentate Helicates

Let's twist again: Actinide quadruple‐stranded helical supramolecular architectures were synthesized in which two capped square‐antiprismatic ThIV centers are coordinated by four bis(bidentate) 4‐acylpyrazolone chelating strands. This example shows a cluster formation caused by incommensurate c...

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Veröffentlicht in:Angewandte Chemie International Edition 2006-10, Vol.45 (39), p.6480-6485
Hauptverfasser: Xu, Jide, Raymond, Kenneth N.
Format: Artikel
Sprache:eng
Schlagworte:
actinides
helical structures
self-assembly
shape analysis
supramolecular chemistry
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Zusammenfassung:Let's twist again: Actinide quadruple‐stranded helical supramolecular architectures were synthesized in which two capped square‐antiprismatic ThIV centers are coordinated by four bis(bidentate) 4‐acylpyrazolone chelating strands. This example shows a cluster formation caused by incommensurate coordination numbers.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200602060