cis-Bis[(3-amino­prop­yl)dimethyl­phosphine-κ2N,P]palladium(II) dichloride methanol solvate

cis-Bis[(3-amino­prop­yl)dimethyl­phosphine-κ2N,P]palladium(II) dichloride methanol solvate

In the title compound, cis‐[Pd(C5H14NP)2]Cl2·CH4O, the coordination geometry around the PdII center is distorted square planar, with a cis‐P2N2 configuration of the two chelating (3‐amino­prop­yl)dimethyl­phosphine (pdmp) ligands. The six‐membered pdmp chelate rings adopt chair conformations, and pa...

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Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2006-10, Vol.62 (10), p.m461-m463
Hauptverfasser: Suzuki, Takayoshi, Hasegawa, Atsushi, Yamaguchi, Hiroshi, Kashiwabara, Kazuo, Takagi, Hideo D.
Format: Artikel
Sprache:eng
Schlagworte:
Condensed matter: structure, mechanical and thermal properties
Crystalline state (including molecular motions in solids)
Exact sciences and technology
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
Theory of crystal structure, crystal symmetry
calculations and modeling
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Beschreibung
Zusammenfassung:In the title compound, cis‐[Pd(C5H14NP)2]Cl2·CH4O, the coordination geometry around the PdII center is distorted square planar, with a cis‐P2N2 configuration of the two chelating (3‐amino­prop­yl)dimethyl­phosphine (pdmp) ligands. The six‐membered pdmp chelate rings adopt chair conformations, and pairing of the chairs designates the complex cation as a (Cs)‐chair2 conformer. The distances between the PdII center and the Cl− anions are greater than 4.5 Å, indicating no obvious inter­action.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270106023596