Telluronium Salts Mediated Aziridination of Chiral N-tert-Butylsulfinylimines:  Highly Stereoselective Synthesis of Optically Active Vinylaziridines

Telluronium Salts Mediated Aziridination of Chiral N-tert-Butylsulfinylimines:  Highly Stereoselective Synthesis of Optically Active Vinylaziridines

Optically active cis-2-substituted vinylaziridines are synthesized by the reaction of N-tert-butylsulfinylimines with telluronium ylides with excellent diastereoselectivity in good to excellent yields.

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Veröffentlicht in:Organic letters 2005-12, Vol.7 (26), p.5789-5792
Hauptverfasser: Zheng, Jun-Cheng, Liao, Wei-Wei, Sun, Xiao-Xia, Sun, Xiu-Li, Tang, Yong, Dai, Li-Xin, Deng, Jin-Geng
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container_end_page 5792
container_issue 26
container_start_page 5789
container_title Organic letters
container_volume 7
creator Zheng, Jun-Cheng
Liao, Wei-Wei
Sun, Xiao-Xia
Sun, Xiu-Li
Tang, Yong
Dai, Li-Xin
Deng, Jin-Geng
description Optically active cis-2-substituted vinylaziridines are synthesized by the reaction of N-tert-butylsulfinylimines with telluronium ylides with excellent diastereoselectivity in good to excellent yields.
doi_str_mv 10.1021/ol051921n
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title Telluronium Salts Mediated Aziridination of Chiral N-tert-Butylsulfinylimines:  Highly Stereoselective Synthesis of Optically Active Vinylaziridines
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