Telluronium Salts Mediated Aziridination of Chiral N-tert-Butylsulfinylimines:  Highly Stereoselective Synthesis of Optically Active Vinylaziridines

Telluronium Salts Mediated Aziridination of Chiral N-tert-Butylsulfinylimines:  Highly Stereoselective Synthesis of Optically Active Vinylaziridines

Optically active cis-2-substituted vinylaziridines are synthesized by the reaction of N-tert-butylsulfinylimines with telluronium ylides with excellent diastereoselectivity in good to excellent yields.

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Veröffentlicht in:Organic letters 2005-12, Vol.7 (26), p.5789-5792
Hauptverfasser: Zheng, Jun-Cheng, Liao, Wei-Wei, Sun, Xiao-Xia, Sun, Xiu-Li, Tang, Yong, Dai, Li-Xin, Deng, Jin-Geng
Format: Artikel
Sprache:eng
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Zusammenfassung:Optically active cis-2-substituted vinylaziridines are synthesized by the reaction of N-tert-butylsulfinylimines with telluronium ylides with excellent diastereoselectivity in good to excellent yields.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol051921n