Covalent Functionalization: Towards Soluble Multiwalled Boron Nitride Nanotubes

Playing with the band: Long alkyl chains are bound to boron nitride nanotubes (BNNTs) from the reaction of stearoyl chloride with amino groups on the BNNTs; the resulting functionalized BNNTs (see picture) are soluble in many organic solvents. Cathodoluminescence and UV/Vis absorption experiments in...

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Veröffentlicht in:Angewandte Chemie International Edition 2005-12, Vol.44 (48), p.7932-7935
Hauptverfasser: Zhi, Chunyi, Bando, Yoshio, Tang, Chengchun, Honda, Susumu, Sato, Kazuhiko, Kuwahara, Hiroaki, Golberg, Dmitri
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Sprache:eng
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Zusammenfassung:Playing with the band: Long alkyl chains are bound to boron nitride nanotubes (BNNTs) from the reaction of stearoyl chloride with amino groups on the BNNTs; the resulting functionalized BNNTs (see picture) are soluble in many organic solvents. Cathodoluminescence and UV/Vis absorption experiments indicate that the long alkyl chains may induce drastic changes in the band structure of BNNTs.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200502846