Synthesis of an Aluminum Spirocyclic Hybrid with an Inorganic B2O3 and an Organic C3N2 Core

Synthesis of an Aluminum Spirocyclic Hybrid with an Inorganic B2O3 and an Organic C3N2 Core

The reaction of LAl (L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) or LAlH2 with PhB(OH)2 yields the unprecedented spirocyclic LAl[(OBPh)2O] compound. The former reaction proceeds under hydrogen formation and simultaneous oxidation of the aluminum(I).

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Veröffentlicht in:Journal of the American Chemical Society 2006-09, Vol.128 (38), p.12406-12407
Hauptverfasser: Yang, Zhi, Ma, Xiaoli, Oswald, Rainer B, Roesky, Herbert W, Noltemeyer, Mathias
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container_end_page 12407
container_issue 38
container_start_page 12406
container_title Journal of the American Chemical Society
container_volume 128
creator Yang, Zhi
Ma, Xiaoli
Oswald, Rainer B
Roesky, Herbert W
Noltemeyer, Mathias
description The reaction of LAl (L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) or LAlH2 with PhB(OH)2 yields the unprecedented spirocyclic LAl[(OBPh)2O] compound. The former reaction proceeds under hydrogen formation and simultaneous oxidation of the aluminum(I).
doi_str_mv 10.1021/ja064035w
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subjects Chemistry
Exact sciences and technology
General and physical chemistry
title Synthesis of an Aluminum Spirocyclic Hybrid with an Inorganic B2O3 and an Organic C3N2 Core
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